Abstract
The application perspective of aerogel glazings in energy efficient buildings has been discussed by evaluating their energy efficiency, process economics, and environmental impact. For such a purpose, prototype aerogel glazing units have been assembled by incorporating aerogel granules into the air cavity of corresponding double glazing units, which enables an experimental investigation on their physical properties and a subsequent numerical simulation on their energy performance. The results show that, compared to the double glazing counterparts, aerogel glazings can contribute to about 21% reduction in energy consumptions related to heating, cooling, and lighting; payback time calculations indicate that the return on investment of aerogel glazing is about 4.4 years in a cold climate (Oslo, Norway); moreover, the physical properties and energy performance of aerogel glazings can be controlled by modifying the employed aerogel granules, thus highlighting their potential over other glazing technologies for window retrofitting towards energy efficient buildings. The results also show that aerogel glazings may have a large environmental impact related to the use of silica aerogels with high embodied energies and potential health, safety and environment hazards, indicating the importance of developing guidelines to regulate the use of aerogel glazings.
ABSTRACT
The path toward energy-efficient buildings with a low or zero carbon footprint, e.g. zero energy and zero emission buildings, involves the development of high-performance thermal insulation, aiming at reaching thermal conductivities far below 20 mW/(mK). Applying such superinsulation will allow the construction of relatively thin building envelopes yet maintaining a high thermal resistance, thus also increasing the architectural design possibilities. A vacuum insulation panel (VIP) represents a stateof-the-art thermal insulation solution with a thermal conductivity of typical 4 mW/(mK) in the pristine and non-aged condition. However, the VIPs have issues with fragility, perforation vulnerability, increasing thermal conductivity during time and lack of building site adaption by cutting as four cardinal weaknesses, in addition to heat bridge effects and relatively high costs. Therefore, the VIPs of today do not represent a robust solution. Hence, our aim is from theoretical principles, utilizing the Knudsen effect for reduced thermal gas conductance in nanopores, to develop experimentally a high-performance nano insulation material (NIM). This work presents the current status of the development of NIM as hollow silica nanospheres (HSNS) in our laboratories, from the experimental synthesis to the material characterization by e.g. thermal conductivity measurements. One attempted approach for tailor-making HSNS is the sacrificial template method and optimization of the sphere diameter and shell thickness with respect to low thermal conductivity. The results so far indicate that HSNS represent a promising candidate for achieving the high-performance thermal superinsulation for application in the buildings of tomorrow.
Summary
This chapter reports an approach to enhance the mechanical strength of silica aerogels via densification. Although the loss of porosity and consequently the increase of thermal conductivity of silica aerogels represent drawbacks related to the densification process, a combination of enhanced mechanical performance and optical transparency indicates that the densificated silica aerogels may be used as new glass material for window glazing application. Preliminary experimental results indicate lightweight (density 1.8 g/cm3, compared to 2.5 g/cm3 for float glass) and thermal insulating (thermal conductivity k ≈ 0.18 W/(mK), compared to about 0.92 W/(mK) for float glass) aerogel glass materials with high visible transparency (Tvis ≈ 95.4% at 500 nm, compared to 92.0% for float glass) can be achieved by annealing an acid-catalyzed silica aerogel precursor at 700 °C. Typical elastic modulus Er of the obtained aerogel glass materials is about 6.42 GPa, which can be further enhanced by, e.g., increasing the annealing temperatures.
Abstract
Glass represents an important and widely used building material, and crucial aspects to be addressed include thermal conductivity, visible light transmittance, and weight for windows with improved energy efficiency. In this work, by sintering monolithic silica aerogel precursors at elevated temperatures, aerogel glass materials were successfully prepared, which were characterized by low thermal conductivity [k ≈ 0.17–0.18 W/(mK)], high visible transparency (Tvis ≈ 91–96 % at 500 nm), low density (ρ ≈ 1.60–1.79 g/cm3), and enhanced mechanical strength (typical elastic modulus Er ≈ 2.0–6.4 GPa). These improved properties were derived from a series of successive gelation and aging steps during the desiccation of silica aerogels. The involved sol → gel → glass transformation was investigated by means of thermo-gravimetric analysis, scanning electron microscopy, nanoindentation, and Fourier transform infrared spectroscopy. Strategies of improving further the mechanical strength of the obtained aerogel glass materials are also discussed.
Abstract
The application of traditional thermal insulation materials requires thicker building envelopes in order to satisfy the requirements of the emerging zero energy and zero emission buildings. This work summarizes the steps from the state-of-theart thermal insulation materials and solutions, like vacuum insulation panels (VIP), gas-filled panels (GFP) and aerogels which all have various drawbacks, to our concepts and experimental investigations for making superinsulation materials (SIM) like e.g. nano insulation materials (NIM).